Back in the 1800’s, Ludwig Boltzmann (1844-1906) developed the idea of entropy and thermodynamics, which have been the main-stay of chemistry and physics ever since. Long before atoms were identified, Boltzmann had used them in designing his theory of statistical mechanics, which related entropy to the number of possible statistical states these particles could occupy. His famous formula

**S = k log W**

is even inscribed on his tombstone! His frustrations with the anti-atomists who hated his crowning achievement ‘statistical mechanics’ led him in profound despair to commit suicide in 1906.

If you flip a coin 4 times, it is unlikely that all 4 flips will result in all-heads or all-tails. It is far more likely that you will get a mixture of heads and tails. This is a result of their being a total of 2^4 = 16 possible outcomes or ‘states’ for this system, and the state with all heads or all tails occur only 1/16 of the time. Most of the states you will produce have a mixture of heads and tails (14/16). Now replace the coin flips by the movement of a set of particles in three dimensions.

Boltzmann’s statistical mechanics related the number of possible states for N particles moving in 3-dimensional space, to the entropy of the system. It is more difficult to calculate the number of states than for the coin flip example above, but it can be done using his mathematics, and the result is the ‘W’ in his equation **S = k Log W**. The bottom line is that, the more states available to a collection of particles (for example atoms of a gas), the higher is the entropy given by . How does a gas access more states? One way is for you to turn up its temperature so that the particles are moving faster. This means that as you increase the temperature of a gas, its entropy increases in a measurable way.

Cosmologically, as our universe expands and cools, its entropy is actually increasing steadily because more and more space is available for the particles to occupy even as they are moving more slowly as the temperature declines. The Big Bang event itself, even at its unimaginably high temperature was actually a state of very low entropy because even though [particles were moving near the speed of light, there was so little space for matter to occupy!

For random particles in a gas colliding like billiard balls, with no other organizing forces acting on them, (called the kinetic theory of gases), we can imagine a collection of 100 red particles clustered in one corner of a box, and 1000 other blue particles located elsewhere in the box. If we were to stumble on a box of 1100 particles that looked like this we would immediately say ‘how odd’ because we sense that as the particles jostled around the 100 red particles would quickly get uniformly spread out inside the box. This is an expression of their being far more available states where the red balls are uniformly mixed, than states where they are clustered together. This is also a statement that the clustered red balls is a lower-entropy version of the system, and the uniformly-mixed version is a higher form of entropy. So we would expect that the system evolves from lower to higher entropy as the red particles diffuse through the box: Called the Second Law of Thermodynamics.

**Boltzmann Brains.**

The problem is that given enough time, even very rare states can have a non-zero probability of happening. With enough time and enough jostling, we could randomly find the red balls once again clustered together. It may take billions of years but there is nothing that stands in the way of this happening from statistical principles. Now let’s suppose that instead of just a collection of red balls, we have a large enough system of particles that some rare states resemble any physical object you can imagine: a bacterium, a cell phone, a car…even a human brain!

A human brain is a collection of particles organized in a specific way to function and to store memories. In a sufficiently large and old universe, there is no obvious reason why such a brain could not just randomly assemble itself like the 100 red particles in the above box. It would be sentient, have memories and even senses. None of its memories would be of actual events it experienced but simply artificial reconstructions created by just the right neural pathways randomly assembled. It would remember an entire lifetime to date without having actually lived or occupied any of the events in space and time.

When you calculate the probability for such a brain to evolve naturally in a low-entropy universe like ours rather than just randomly assembling itself you run into a problem. According to Boltzmann’s cosmology, our vast low-entropy and seemingly highly organized universe is embedded in a much larger universe where the entropy is much higher. It is far less likely that our organized universe exists in such a low entropy state conducive to organic evolution than a universe where a sentient brain simply assembles itself from random collisions. In any universe destined to last for eternity, it will rapidly be populated by incorporeal brains rather than actual sentient creatures! This is the Paradox of the Boltzmann Brain.

Even though Creationists like to invoke the Second Law to deny evolution as a process of random collisions, the consequence of this random idea about structure in the universe says that we are actually all Boltzmann Brains not assembled by evolution at all. It is, however, of no comfort to those who believe in God because God was not involved in randomly assembling these brains, complete with their own memories!

So how do we avoid filling our universe with the abomination of these incorporeal Boltzman Brains?

**The Paradox Resolved**

First of all, we do not live in Boltzmann’s universe. Instead of an eternally static system existing in a finite space, direct observations show that we live in an expanding universe of declining density and steadily increasing entropy.

Secondly, it isn’t just random collisions that dictate the assembly of matter (a common idea used by Creationists to dismantle evolution) but a collection of specific underlying forces and fundamental particles that do not come together randomly but in a process that is microscopically determined by specific laws and patterns. The creation of certain simple structures leads through chemical processes to the inexorable creation of others. We have long-range forces like gravity and electromagnetism that non-randomly organize matter over many different scales in space and time.

Third, we do not live in a universe dominated by random statistical processes, but one in which we find regularity in composition and physical law spanning scales from the microscopic to the cosmic, all the way out to the edges of the visible universe. When two particles combine, they can stick together through chemical forces and grow in numbers from either electromagnetic or gravitational forces attracting other particles to the growing cluster, called a nucleation site.

Fourth, quantum processes and gravitational processes dictate that all existing particles will eventually decay or be consumed in black holes, which will evaporate to destroy all but the most elementary particles such as electrons, neutrinos and photons; none of which can be assembled into brains and neurons.

The result is that Boltzmann Brains could not exist in our universe, and will not exist even in the eternal future as the cosmos becomes more rarefied and reaches its final and absolute thermodynamic equilibrium.

The accelerated expansion of the universe now in progress will also insure that eventually all complex collections of matter are shattered into individual fundamental particles each adrift in its own expanding and utterly empty universe!

Have a nice day!

**Check back here on Tuesday, May 9 for my next topic!**